Ring Flip

Author:   Lambert M. Surhone ,  Mariam T. Tennoe ,  Susan F. Henssonow
Publisher:   VDM Publishing House
ISBN:  

9786131278860


Pages:   122
Publication Date:   16 August 2010
Format:   Paperback
Availability:   In Print   Availability explained
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Ring Flip


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Overview

High Quality Content by WIKIPEDIA articles! Ring flipping (also known as ring inversion or ring reversal) is a phenomenon involving the interconversion (by rotation) about single bonds of cyclic conformers having equivalent ring shapes but not necessarily equivalent spatial positions of substituent atoms. The six-membered ring of the alkane, cyclohexane, has the 'chair' as its preferred conformation and through proton NMR it would be expected that the produced spectrum would show the different sorts of protons (axial and equatorial) resonating at different frequencies, and so two signals would be seen, due to the protons being in slightly different chemical environments. However, only one signal can be seen as the two isomers are rapidly interconverting. This also occurs with monosubstituted cyclohexanes. This changes with the use of low temperature, as the two isomers visible interconvert much more slowly than at room temperature.

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Author:   Lambert M. Surhone ,  Mariam T. Tennoe ,  Susan F. Henssonow
Publisher:   VDM Publishing House
Imprint:   VDM Publishing House
Dimensions:   Width: 22.90cm , Height: 0.70cm , Length: 15.20cm
Weight:   0.190kg
ISBN:  

9786131278860


ISBN 10:   6131278865
Pages:   122
Publication Date:   16 August 2010
Audience:   General/trade ,  General
Format:   Paperback
Publisher's Status:   Active
Availability:   In Print   Availability explained
This item will be ordered in for you from one of our suppliers. Upon receipt, we will promptly dispatch it out to you. For in store availability, please contact us.

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