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OverviewDeniz Yilmaz' thesis describes a combination of orthogonal supramolecular interactions for the design of functional monolayer architectures on surfaces, that can be used as chemical and biosensors in a wide range of applications. The term “orthogonal supramolecular interactions” refers to non-covalent interactions that do not influence each other's assembly properties. Orthogonal self-assembly thus allows extended control over the self-assembly process and promotes new materials properties. The first part of the thesis employs orthogonal host-guest and lanthanide-ligand coordination interaction motifs to create supramolecular luminescent monolayers. The second part of the thesis describes the fabrication of functional monolayers on silicon and gold substrates for applications in electronics. The results illustrate the power of weak supramolecular interactions to direct the immobilization of functional systems on surfaces. The combination of host-guest and lanthanide-ligand coordination interaction motifs on surfaces demonstrates that hybrid, multifunctional supramolecular monolayers can be fabricated by integrating different non-covalent interactions in the same system. This combination opens up new avenues for the fabrication of complex hybrid organic-inorganic materials and stimuli-responsive surfaces. Their utility is demonstrated through applications of the functional interfaces to biosensing and nanotechnology. Full Product DetailsAuthor: Mahmut Deniz YilmazPublisher: Springer-Verlag Berlin and Heidelberg GmbH & Co. KG Imprint: Springer-Verlag Berlin and Heidelberg GmbH & Co. K Edition: Softcover reprint of the original 1st ed. 2012 Volume: 117 Dimensions: Width: 15.50cm , Height: 0.70cm , Length: 23.50cm Weight: 0.454kg ISBN: 9783662522202ISBN 10: 3662522209 Pages: 101 Publication Date: 23 August 2016 Audience: Professional and scholarly , Professional & Vocational Format: Paperback Publisher's Status: Active Availability: Manufactured on demand  We will order this item for you from a manufactured on demand supplier. Table of ContentsOrthogonal Supramolecular Interaction Motifs for Functional Monolayer Architectures.- Expression of Sensitized Eu3+ Luminescence at a Multivalent Interface.- Ratiometric Fluorescent Detection of an Anthrax Biomarker at Molecular Printboards.- A Supramolecular Sensing Platform in a Microfluidic Chip.- Local Doping of Silicon Using Nanoimprint Lithography and Molecular Monolayers.- Fabrication of Two-Dimensional Organic Spin Systems on Gold.ReviewsAuthor InformationTab Content 6Author Website:Countries AvailableAll regions |
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