Overview

Full Product Details

Author:   Arun Lal Srivastav ,  Lata Rani ,  Jyotsna Kaushal ,  Tien Duc Pham
Publisher:   Wiley-VCH Verlag GmbH
Imprint:   Blackwell Verlag GmbH
Dimensions:   Width: 17.00cm , Height: 1.50cm , Length: 24.40cm
Weight:   0.680kg
ISBN:  

9783527351923

ISBN 10:   3527351922
Pages:   416
Publication Date:   11 October 2023
Audience:   Professional and scholarly ,  Professional & Vocational
Format:   Hardback
Publisher's Status:   Active
Availability:   Out of stock  
The supplier is temporarily out of stock of this item. It will be ordered for you on backorder and shipped when it becomes available.

Table of Contents

Preface xiii 1 Application of MOFs on Removal of Emerging Water Contaminants 1 Nguyen Minh Viet, Tran Thi Viet Ha, and Nguyen Le Minh Tri Abbreviated list 1 1.1 Introduction 1 1.1.1 Sources of Emerging Water Contaminants 1 1.1.2 Emerging Water Contaminants Treatment Methods 2 1.1.3 MOFs as Exceptional Materials for Water Remediation 7 1.2 MOFs Strategies in Water Remediation 7 1.2.1 Adsorption 8 1.2.2 Catalyst 10 1.2.3 Synergistic Effect of Adsorption and Photocatalyst 12 1.3 Emerging Water Contaminants by MOFs 12 1.3.1 Organic Dyes 12 1.3.2 Adsorption 12 1.3.3 Photocatalytic and Electrostatic Activities 13 1.3.4 PPCPs 13 1.3.5 Adsorption 14 1.3.6 Photocatalytic Activities 14 1.3.7 Herbicides and Pesticides 15 1.3.8 Adsorption 15 1.3.9 Photocatalytic Activities 16 1.3.10 Industrial Compounds/By-products 17 1.3.11 Adsorption 17 1.3.12 Photocatalytic Activities 17 1.4 Challenges and Perspective in Using MOFs for the Removal of Emerging Water Contaminants 17 1.5 Conclusion 18 2 Metal-Organic Frameworks and Their Stepwise Preparatory Methods (Synthesis) for Water Treatment 27 Debarati Chakraborty and Prof. Siddhartha S. Dhar 2.1 Introduction 27 2.2 Classification of Metal-Organic Frameworks 28 2.3 Synthesis of MOFs 29 2.3.1 Conventional Solvothermal/Hydrothermal and Non-Solvothermal Method 29 2.3.2 Room-Temperature Synthesis 30 2.3.3 Unconventional Methods 30 2.4 Alternative Synthesis Methods 31 2.4.1 Microwave-Assisted Synthesis 31 2.4.2 Electrochemical Synthesis 32 2.4.3 Sonochemical Synthesis 34 2.4.4 Surfactant-Assisted Synthesis 35 2.4.5 Layer-by-Layer Synthesis 36 2.5 Factors Affecting the Synthesis of MOFs 37 2.5.1 Solvents 37 2.6 Temperature and pH Effects on the Synthesis of MOFs 38 2.7 Water Regeneration and Wastewater Treatment Using MOF Membranes 39 2.8 Membrane Filtration 39 2.9 Microfiltration (MF) 39 2.10 Ultrafiltration (UF) 40 2.11 Nanofiltration (NF) 40 2.12 Reverse Osmosis (RO) and Forward Osmosis (FO) 41 2.13 Membrane Distillation (MD) 41 2.14 Membrane Pervaporation (PV) 42 2.15 Conclusion 43 3 Application of MOFs in the Removal of Pharmaceutical Waste from Aquatic Environments 53 Gagandeep Kaur, Parul Sood, Lata Rani, and Nitin Verma 3.1 Introduction 53 3.2 The Potential of MOFs and Their Analogs to Resist Water Stability 55 3.3 Methods for the Development and Design of Aqueous-Stable Composites of Metal-Organic Frameworks 56 3.4 Synthesis and Design of Water-Stable MOF-Derived Materials 57 3.5 MOFs and Their Hybrids as Versatile Adsorbents for Capturing Pharmaceutical Drugs 58 3.6 MILs and Their Derived Compounds 58 3.7 Pristine MILs 58 3.8 MILs Composites 59 3.9 MILs-Derived Materials 60 3.10 ZIFs and Their Derived Compounds 60 3.11 Pristine ZIFs 60 3.12 ZIFs Composites 61 3.13 Materials Derived from ZIFs 61 3.14 UiOs Composite Materials 62 3.15 UiOs-Derived Materials 63 3.16 Pharmaceutical Drug Resistance 63 3.17 Conclusion 64 4 Efficiency of MOFs in Water Treatment Against the Emerging Water Contaminants Such as Endocrine Disruptors, Pharmaceuticals, Microplastics, Pesticides, and Other Contaminants 73 Jogindera Devi and Ajay Kumar 4.1 Introduction 73 4.2 Chemical Contaminants: Those Mysterious Ingredients in Ground and Surface Water 74 4.2.1 Endocrine Disruptors (EDs) 74 4.2.2 Microplastics (MPs) 74 4.2.3 Contaminants from the Agriculture Sector 75 4.2.4 Pharmaceutical Effluents 75 4.3 MOFs 76 4.3.1 MOF Stability in the Aqueous Phase 77 4.3.2 Improving the Water Stability of MOFs: General Enhancement Strategies 77 4.4 Possibilities for Wastewater Treatment Applications Using MOFs 78 4.4.1 MOF-Supported Adsorption & Photocatalysis 79 4.4.2 π-π Interactions 80 4.4.3 Electrostatic Interactions 80 4.4.4 Hydrophobic Interactions 81 4.4.5 H-Bonding 82 4.5 Use of MOFs for Water Remediation: Issues & Perspectives 82 4.6 Future 85 4.7 Conclusions 85 5 Metal-Organic Frameworks for Wastewater Contaminants Removal 95 Khushbu Sharma, Priyanka Devi, and Prasann Kumar 5.1 Introduction 95 5.2 Aqueous Phase MOF Stability 96 5.3 MOF Degradation in Water 97 5.4 Influence of MOF Structure 97 5.5 2D Nanostructured Coating 97 5.6 3D Nanostructure of MOF 98 5.7 MOF-Based Materials’ Adsorption Processes for Heavy Metal Oxyanion 99 5.8 Remediation Through Perfect MOFs 102 5.9 Interaction of MOFs with Other Species 102 5.10 With the Use of MOF Composites 103 5.11 Removal of Metal Ions through Adsorption 105 5.12 MOF Composites are Used for Removal 106 5.13 COFs are a New Class of Materials that Have Similar MOF Structures 107 5.14 Application of MOF Composites 108 5.15 Gas Separation and Adsorption 109 5.16 MOF Composites 110 5.17 Agrochemical Adsorption and Removal 111 5.18 Pharmaceutical and Personal Care Adsorption Removal Products (PPCPs) 112 5.19 MOFs for Photocatalytic Elimination of Organic Pollutants 113 5.20 Conclusion 113 Acknowledgment 114 Author Contributions 114 Conflicts of Interest 115 6 “Green Applications of Metal-Organic Frameworks for Wastewater Treatment” 119 Ankita Saini, Sunil Kumar Saini, and Parul Lakra 6.1 Introduction 119 6.2 Role of Green Chemistry in Preparation of MOFs 122 6.3 Green Application of MOFs in the Removal of Contaminants from Wastewater 124 6.3.1 MOFs for the Removal of Inorganic Contaminants 125 6.3.2 MOFs for the Removal of Organic Contaminants 136 6.4 Conclusion and Future Prospects 138 6.5 Conflict of Interest 139 7 Case Studies (Success Stories) on the Application of Metal-Organic Frameworks (MOFs) in Wastewater Treatment and Their Implementations; Review 151 Arpit Kumar, Mahesh Rachamalla, and Akshat Adarsh 7.1 Introduction 151 7.2 Metal-Organic Framework (MOF) 154 7.2.1 Properties and Applications of MOFs 154 7.3 Applications of MOFs in Wastewater Treatment: Case Studies 156 7.3.1 Forward Osmosis (FO) Membranes 159 7.3.2 Application and Effectiveness 159 7.3.3 Reverse Osmosis (RO) Membranes 160 7.3.4 Application and Effectiveness 161 7.3.5 Nano Filter (NF) Membranes 162 7.3.6 Application and Effectiveness 163 7.3.7 Ultrafiltration (UF) Membranes 164 7.3.8 Application and Effectiveness 165 Summary 166 Acknowledgment 167 8 Prospects and Potentials of Microbial Applications on Heavy-Metal Removal from Wastewater 177 Dipankar Ghosh, Shubhangi Chaudhary, and Snigdha Dhara 8.1 Introduction 177 8.2 Mainstream Avenues to Remediate Heavy Metals in Wastewater 178 8.3 The Microbial Recycling Approach 179 8.4 General Overview of Heavy-Metal Pollution in Wastewater 181 8.5 Techniques for Heavy-Metal Removal 183 8.6 Microbial and Biological Approaches for Removing Heavy Metals from Wastewater 186 8.7 Biological Remediation Approaches for Heavy-Metal Removal 187 8.8 Microbial Bioremediation Approaches 190 8.9 Bioengineering Approaches on Microbes for Improving Heavy-Metal Removal from Wastewater 191 8.10 Conclusion 192 Acknowledgment 193 9 Removal of Organic Contaminants from Aquatic Environments Using Metal-Organic Framework (MOF) Based Materials 203 Linkon Bharali and Siddhartha S. Dhar 9.1 Introduction 203 9.2 MOF-Based Materials 205 9.2.1 MOF—Metal Nanoparticle Materials 205 9.2.2 MOF–MO Materials 206 9.2.3 MOF–Quantum Dot Materials 207 9.2.4 MOF–Silica Materials 207 9.2.5 MOF–Carbon Materials 208 9.2.6 Core—shell Structures of MOFs 209 9.2.7 MOF–Enzyme Materials 210 9.2.8 MOF–Organic Polymer Materials 210 9.3 Environmental Effects of MOF-Based Materials 211 9.4 Conclusion 215 10 Reformed Metal-Organic Frameworks (MOFs) for Abstraction of Water Contaminants – Heavy-Metal Ions 227 Prakash B. Rathod, Rahul A. Kalel, Mahendra Pratap Singh Tomar, Akshay Chandrakant Dhayagude, and Parshuram D. Maske 10.1 Introduction 227 10.2 Metal-Organic Frameworks 228 10.3 Sorption Enrichment by Modification of MOFs 229 10.4 Toxic-Metal Ion Adsorption by MOFs 231 10.4.1 MOFs for Mercury Adsorption 231 10.4.2 MOFs for Lead Adsorption 234 10.4.3 MOFs for Cadmium Adsorption 235 10.4.4 MOFs for Chromium Removal 236 10.4.5 MOFs for Arsenic Removal 238 10.4.6 MOFs for Heavy Metals Phosphate Removal 239 10.4.7 MOFs for Nickel Adsorption 240 10.4.8 MOFs for Selenium Adsorption 240 10.4.9 MOFs for Uranium Adsorption 240 10.5 Future Perspective 241 10.6 Future Scope 241 10.7 Conclusions 242 11 Application of Algal-Polysaccharide Metal-Organic Frameworks in Wastewater Treatment 251 Dharitri Borah, Jayashree Rout, and Thajuddin Nooruddin 11.1 Introduction 251 11.1.1 Water Pollutants and Sources 251 11.1.2 Common Wastewater Treatment Techniques 252 11.1.3 Metal-Organic Frameworks for Wastewater Treatment 252 11.1.4 Polysaccharide-Metal-organic Frameworks (Ps-MOFs) 253 11.2 Polysaccharides in Algae/cyanobacteria (AlPs) 254 11.2.1 Polysaccharides in Cyanophyceae 254 11.2.2 Polysaccharides in Chlorophyceae 258 11.2.3 Polysaccharides in Rhodophyceae 258 11.2.4 Polysaccharides in Phaeophyceae 259 11.3 Synthesis of Algal Polysaccharide MOFs (ALPs-MOFs) 259 11.3.1 Alginate-MOFs 260 11.3.2 Cellulose-MOFs 262 11.3.3 Agar-MOFs 263 11.4 Characterization of AlP-MOFs 264 11.5 Adsorption Mechanism of AlPs-MOFs 268 11.6 Regeneration of AlPs-MOFs 271 11.7 Conclusion and Future Prospects 272 12 Ecological Risk Assessment of Heavy Metal Pollution in Water Resources 281 Swati Singh and K. V. Suresh Babu 12.1 Introduction 281 12.2 Natural and Anthropogenic Sources of Heavy Metals in the Environment 282 12.3 Impacts of Heavy Metal Pollution 283 12.4 Water Quality Assessment Using Pollution Indices 286 12.4.1 Heavy Metal Pollution Index (HPI) 287 12.4.2 Statistical Technique 288 12.5 MOFs for Heavy Metal Contaminant Removal from Water 289 12.6 Conclusion 290 13 Organic Contaminants in Aquatic Environments: Sources and Impact Assessment 299 Shipa Rani Dey, Priyanka Devi, and Prasann Kumar 13.1 Introduction 299 13.2 The Various Forms and Causes of Chemical Pollutants 300 13.3 Increasing Contaminant Occurrence in Aquatic Systems 302 13.4 Identifying Potential Points of Entry for New Pollutants into Aquatic Systems 304 13.5 Groups of Trace Pollutants and ECs 305 13.5.1 Polybrominated Diphenyl Ethers (PBDEs) 305 13.6 Pharmaceuticals and Personal Care Products (PPCPs) 306 13.7 Concentrations of Micropollutants in Aquatic Organisms 308 13.8 Methods for Micropollutant Removal 308 13.9 Mitigation of Aqueous Micropollutants 310 13.10 Chemical Treatment of Wastewater Discharge 311 13.11 Conclusion 311 Acknowledgment 312 Authors Contributions 312 Conflicts of Interest 312 14 Physicochemical Properties and Stability of MOFs in Water Environments 319 Priya Saharan, Vinit Kumar, Indu Kaushal, Ashok Kumar Sharma, Narender Ranga, and Dharmender Kumar 14.1 Introduction 319 14.2 Background and Future Scope of MOFs 320 14.3 Techniques Used to Determine the Physicochemical Properties of MOFs 320 14.3.1 Powder X-Ray Diffraction (PXRD) 321 14.3.2 BET Surface Area Analyzer 321 14.3.3 Electron Microscopy and Elemental Analysis 322 14.3.4 Thermogravimetric Analysis (TGA) 322 14.3.5 Fourier-Transform Infrared (FT-IR) 322 14.4 Physicochemical Properties of MOFs and Their Effects on Various Applications 322 14.4.1 Porosity 322 14.4.2 Size and Morphology 323 14.4.3 Chemical Reactivity 325 14.4.4 Chemical Stability 327 14.4.5 Thermal Stability 329 14.4.6 Mechanical Stability 331 14.5 Conclusion 332 15 Metal-Organic Framework Adsorbents for Indutrial Heavy-Metal Wastewater Treatment 337 Gopal Sonkar 15.1 Introduction 337 15.2 The Applications of MOFs 338 15.3 Comparison Between MOF Adsorbents and Bio-Based Adsorbents 338 15.4 Heavy Metal Contaminant Sources and Impacts 340 15.5 Adsorption 343 15.5.1 The Adsorption Process 343 15.5.2 Adsorption Mechanisms 344 15.5.3 Adsorption Parameters 344 15.5.4 Different Processes for Methods of Adsorption 345 15.6 A Specific Review on Tea-Waste Adsorption 347 15.7 Conclusions 348 16 Evaluation of MOF Applications for Groundwater Arsenic Mitigation of the Middle Ganga Plains of Bihar, India 355 Arun Kumar, Vivek Raj, Mohammad Ali, Abhinav, Mahesh Rachamalla, Dhruv Kumar, Arti Kumari, Rakesh Kumar, Prabhat Shankar, and Ashok Kumar Ghosh 16.1 Arsenic Contamination in the Groundwater of Bihar 355 16.2 Status of Groundwater Arsenic Exposure in the Affected Population 361 16.2.1 Mitigation Status in the Arsenic-Exposed Area of Bihar 364 16.2.2 Application of MOFs in Arsenic Removal from Groundwater 364 16.2.3 Conclusion 365 Index 375

Reviews

Author Information

Arun Lal Srivastav, PhD, Assistant Professor, Chitkara University School of Engineering and Technology, Chitkara University, Himachal Pradesh, India. Lata Rani, PhD, Assistant Professor, Chitkara University School of Pharmacy, Chitkara University, Himachal Pradesh, India. Jyotsna Kaushal, PhD, Professor, Centre for Water Sciences, Chitkara University Institute of Engineering & Technology, Chitkara University, Punjab, India. Tien Duc Pham, PhD, Associate Professor, Faculty of Chemistry, University of Science, Vietnam National University, Hanoi, Vietnam.

Tab Content 6

Author Website:  

Customer Reviews

Recent Reviews

No review item found!

Add your own review!

Countries Available

All regions