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OverviewThere is a wide variety of heterogeneous fluid systems that possess interphase surfaces. This monograph is devoted to pioneering studies in nonequilibrium statistical mechanics of such systems. Starting from the Liouville equation, the equations of surface hydrodynamics are derived with allowance for discontinuities of thermodynamic parameters of interphase boundaries. Brownian motion of a large solid particle in a fluid and nucleation are treated as results of fluctuations of flows across particle surfaces. With the use of the Gibbs method, a shock wave in a gas is considered as a sort of an interphase surface, and the surface tension of a shock front is introduced for the first time. Full Product DetailsAuthor: Andrei G. BashkirovPublisher: Taylor & Francis Inc Imprint: CRC Press Inc Dimensions: Width: 15.20cm , Height: 1.50cm , Length: 22.90cm Weight: 0.430kg ISBN: 9780849328602ISBN 10: 0849328608 Pages: 174 Publication Date: 09 March 1995 Audience: College/higher education , Professional and scholarly , Postgraduate, Research & Scholarly , Professional & Vocational Format: Hardback Publisher's Status: Active Availability: In Print This item will be ordered in for you from one of our suppliers. Upon receipt, we will promptly dispatch it out to you. For in store availability, please contact us. Table of ContentsPrefaceZubarev Method of Nonequilibrium Statistical OperatorContracted Description of a Statistical SystemQuasiequilibrium Distribution FunctionNonequilibrium Distribution FunctionTransport Phenomena at Interfaces and the Problem of Boundary Conditions in HydrodynamicsIntroductionGeometric Description of the Surface Local Equilibrium DistributionGibbs Adsorption EquationConservation LawsEquations of Ideal HydrodynamicsNonequilibrium Distribution FunctionTransport Equations for Surface FilmsMotion Equations for Excess QuantitiesThe Problem of Boundary Conditions in HydrodynamicsTheory of Capillary Waves DampingShock Waves in Gases as Interface SurfacesIntroductionThe Jump Conditions on Curved DiscontinuitiesEstimation of the Surface Tension CoefficientEquations for Small DisturbancesShock Wave Stability AnalysisNucleation Theory: Fluctuations of Diffusion Flow across the Interface BoundaryIntroductionTotal Nonequilibrium Distribution FunctionNucleation Kinetic EquationNucleation CoefficientEntropy ProductionSecond Quantization ApproachNonisothermal Nucleation TheoryThe Model ExampleBrownian Motion: Momentum Flow Fluctuations on Interphase BoundaryIntroductionMicroscopic Description of the System of Brownian Particle and FluidDerivation of the Kinetic EquationBoundary Conditions on the Surface of the Large ParticleCalculation of the Average Force and the Drag CoefficientBrownian Diffusion of Large Particle in Inhomogeneous FluidOn a Limitation of the TheoryDerivation of the Fokker-Planck Equation for the Point Brownian ParticleKirkwood Friction CoefficientDiffusion of the Point ParticleBrownian Motion of N Spheres in Inhomogeneous FluidsIntroductionThe N-Particle Fokker-Planck EquationThe Smoluchowski EquationBrownian Diffusion of Suspended ParticlesConvective Diffusion of ParticReviewsAuthor InformationAndrei G. Bashkirov Tab Content 6Author Website:Countries AvailableAll regions |