NMR-Untersuchungen an Komplexverbindungen

Author:   H. J. Keller
Publisher:   Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
Edition:   Softcover reprint of the original 1st ed. 1970
Volume:   2
ISBN:  

9783642876394


Pages:   88
Publication Date:   18 April 2012
Format:   Paperback
Availability:   Manufactured on demand   Availability explained
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NMR-Untersuchungen an Komplexverbindungen


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Overview

Nuclear magnetic resonance spectroscopy, which has evolved only within the last 20 years, has become one of the very important tools in chemistry and physics. The literature on its theory and application has grown immensely and a comprehensive and adequate treatment of all branches by one author, or even by several, becomes increasingly difficult. This series is planned to present articles written by experts working in various fields of nuclear magnetic resonance spectroscopy, and will contain review articles as well as progress reports and original work. Its main aim, however, is to fill a gap, existing in literature, by publishing articles written by specialists, which take the reader from the introductory stage to the latest development in the field. The editors are grateful to the authors for the time and effort spent in writing the articles, and for their invaluable cooperation. The Editors NMR-Untersuchungen an Komplexverbindungen H. J. KELLER Anorganisch-chemisches Laboratorium der Technischen Hochschule Munchen Inhalt 1. Einleitung . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 2. Die Theorie der NMR-Parameter. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 2. 1. Verschiebungen. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 2. 2. Die Kopplungskonstanten . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 3. NMR an MetaJI-Komplexen im resten Zustand . . . . . . . . . . . . . . . . . . . . . 10 3. 1. Unterscheidung zwischen ""magnetischen"" und ""nichtmagnetischen"" Festkorpern. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 3. 1. 1. Nichtmagnetische Festkorper . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 3. 1. 1. 1. Direkte Dipol-Dipol-Wechselwirkung . . . . . . . . . . . . . . 10 3. 1. 1. 1. 1. Ausmittelnde Bewegungen . . . . . . . . . . . . . . . . 15 3. 1. 1. 2. Verschiebungen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 3. 1. 2. ""Magnetische"" Festkorper. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 3. 1. 2. 1. Schwache intermolekulare Wechselwirkungen zwischen den Elektronen. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 3. 1. 2. 2. Starke intermolekulare Wechselwirkungen . . . . . . . . . .

Full Product Details

Author:   H. J. Keller
Publisher:   Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
Imprint:   Springer-Verlag Berlin and Heidelberg GmbH & Co. K
Edition:   Softcover reprint of the original 1st ed. 1970
Volume:   2
Dimensions:   Width: 17.00cm , Height: 0.50cm , Length: 24.40cm
Weight:   0.186kg
ISBN:  

9783642876394


ISBN 10:   3642876390
Pages:   88
Publication Date:   18 April 2012
Audience:   Professional and scholarly ,  Professional & Vocational
Format:   Paperback
Publisher's Status:   Active
Availability:   Manufactured on demand   Availability explained
We will order this item for you from a manufactured on demand supplier.
Language:   German

Table of Contents

1. Einleitung.- 2. Die Theorie der NMR-Parameter.- 2.1. Verschiebungen.- 2.2. Die Kopplungskonstanten.- 3. NMR an Metall-Komplexen im festen Zustand.- 3.1. Unterscheidung zwischen „magnetischen“ und „nichtmagnetischen“ Festkörpern.- 3.2. Quadrupoleffekte in der NMR-Spektroskopie.- 4. NMR-Untersuchungen in Lösung.- 4.1. „Hochauflösende“ Spektroskopie an diamagnetischen Metall-Komplexen.- 5. Der Einfluß zeitabhängiger Vorgänge auf die NMR-Spektren.- 5.1. Theoretische Grundlagen.- 5.2. NMR an paramagnetischen Komplexen.- 5.3. Intermolekulare Austauschreaktionen diamagnetischer Komplexe.- 5.4. Intramolekulare Austauschprozesse in diamagnetischen Komplexen.- Literatur.

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