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OverviewThis thesis deals with strongly luminescent lanthanide complexes having novel coordination structures. Luminescent lanthanide complexes are promising candidates as active materials for EL devices, lasers, and bio-sensing applications. The organic ligands in lanthanide complexes control geometrical and vibrational frequency structures that are closely related to the luminescent properties. In most of the previous work, however, lanthanide complexes have high-vibrational frequency C–H units close to the metal center for radiationless transition. In this thesis, the luminescent properties of lanthanide complexes with low-vibrational frequency C–F and P=O units are elucidated in terms of geometrical, vibrational, and chemical structures. The author also describes lanthanide coordination polymers with both high thermal stability (decomposition point > 300°C) and strong-luminescent properties (emission quantum yield > 80%). The author believes that novel studies on the characteristic structures and photophysical properties of lanthanide complexes may open up a frontier field in photophysical, coordination and material chemistry. Full Product DetailsAuthor: Kohei MiyataPublisher: Springer Verlag, Japan Imprint: Springer Verlag, Japan Edition: 2014 ed. Dimensions: Width: 15.50cm , Height: 1.30cm , Length: 23.50cm Weight: 0.336kg ISBN: 9784431549437ISBN 10: 4431549439 Pages: 91 Publication Date: 17 April 2014 Audience: Professional and scholarly , Professional & Vocational Format: Hardback Publisher's Status: Active Availability: Manufactured on demand  We will order this item for you from a manufactured on demand supplier. Table of ContentsGeneral Introduction.- Luminescence Properties of Thermostable Lanthanide Coordination Polymers with Intermolecular Interactions.- Chameleon Luminophore for a Wide Range Temperature-Sensor Composed of Lanthanide Coordination Polymers.- Characteristic Structures and Photophysical Properties of Nona-coordinated Eu(III) Complexes with Tridentate Phosphine Oxides.- Photophysical Properties of Lanthanide Complexes with Asymmetric Dodecahedron Structures.- Solvent-dependent Luminescence of Octa-coordinated Eu(III) Complexes.- Summary.ReviewsAuthor InformationTab Content 6Author Website:Countries AvailableAll regions |
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