Overview

For several years, the two parallel worlds of Molecular Conductors in one hand and Molecular Magnetism in the other have grown side by side, the former essentially based on radical organic molecules, the latter essentially based on the high spin properties of metal complexes. Over the last few years however, organometallic derivatives have started to play an increasingly important role in both worlds, and have in many ways contributed to open several passages between these two worlds. This volume recognizes this important emerging evolution of both research areas. It is not intended to give a comprehensive view of all possible organometallic materials, and polymers for example were not considered here. Rather we present a selection of the most recent research topics where organometallic derivatives were shown to play a crucial role in the setting of conducting and/or magnetic properties in crystalline materials. First, the role of organometallic anions in tet- thiafulvalenium-based molecular conductors is highlighted by Schlueter, while Kubo and Kato describe very recent ortho-metalated chelating ligands appended to the TTF core and their conducting salts. The combination of conducting and magnetic properties and the search for p–d interactions are analyzed in two comp- mentary contributions by Myazaki and Ouahab, while Valade focuses on the only class of metal bis(dithiolene) complexes to give rise to superconductive molecular materials, in association with organic as well as organometallic cations.

Full Product Details

Author:   Marc Fourmigué ,  Lahcène Ouahab
Publisher:   Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
Imprint:   Springer-Verlag Berlin and Heidelberg GmbH & Co. K
Edition:   2009 ed.
Volume:   27
Dimensions:   Width: 15.50cm , Height: 1.80cm , Length: 23.50cm
Weight:   0.521kg
ISBN:  

9783642004070

ISBN 10:   3642004075
Pages:   193
Publication Date:   21 July 2009
Audience:   College/higher education ,  Postgraduate, Research & Scholarly
Format:   Hardback
Publisher's Status:   Active
Availability:   In Print  
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Table of Contents

Tetrathiafulvalene-Based Conductors Containing Organometallic Components.- New Molecular Architecture for Electrically Conducting Materials Based on Unsymmetrical Organometallic-Dithiolene Complexes.- Electroactive Paramagnetic Complexes as Molecular Bricks for ?-d Conducting Magnets.- ?-d Interaction-Based Molecular Conducting Magnets.- Metallocenium Salts of Transition Metal Bisdichalcogenate Anions; Structure and Magnetic Properties.- Conductive Materials Based on M(dmit)2 Complexes and Their Combination with Magnetic Complexes.- Magnetic Properties of Radical, Crystalline Mixed Cyclopentadienyl/Dithiolene Complexes.

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