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OverviewFull Product DetailsAuthor: Paul C. Yates , Paul C. YatesPublisher: Taylor & Francis Ltd Imprint: CRC Press Edition: 3rd edition Weight: 1.180kg ISBN: 9780367488673ISBN 10: 0367488671 Pages: 370 Publication Date: 21 April 2023 Audience: College/higher education , Professional and scholarly , Undergraduate , Professional & Vocational Format: Hardback Publisher's Status: Active Availability: In Print  This item will be ordered in for you from one of our suppliers. Upon receipt, we will promptly dispatch it out to you. For in store availability, please contact us. Table of ContentsPreface Acknowledgements 1 Fundamentals 1.1 Introduction 1.2 Positive and negative numbers 1.2.1 Addition 1.2.2 Subtraction 1.2.3 Multiplication 1.2.4 Division 1.3 Precedence in equations 1.4 Rearranging equations 1.5 Fractions 1.5.1 Identical fractions 1.5.2 Addition and subtraction 1.5.3 Multiplication 1.5.4 Division 1.6 Indices 1.6.1 Multiplication 1.6.2 Division 1.6.3 Raising to a power 1.6.4 Roots 1.6.5 Negative powers 1.7 Standard form Exercises Problems 2 Experimental techniques 2.1 Introduction 2.2 Measurement in chemistry 2.2.1 Decimal places 2.2.2 Significant figures 2.2.3 Combining quantities 2.3 Stoichiometric calculations 2.3.1 Multiplication and division by an integer 2.4 Uncertainty in measurement 2.4.1 Types of uncertainty 2.4.2 Combining uncertainties 2.4.2.1 Determining the maximum possible uncertainty 2.4.2.2 Determining the maximum probable uncertainty 2.4.3 Statistical treatment of uncertainties 2.4.3.1 Statistics using a calculator 2.4.3.2 Statistics using a spreadsheet Exercises Problems 3 Thermodynamics 3.1 Fractions and indices in the equilibrium constant 3.2 Bond enthalpies 3.2.1 Rearranging equations 3.3 The Born-Haber cycle 3.3.1 Combining uncertainties 3.4 Heat capacity 3.4.1 Expansion of brackets 3.4.2 Polynomial expressions 3.4.3 Functions 3.5 Clapeyron equation 3.5.1 Differentiation 3.6 Clausius-Clapeyron equation 3.6.1 Logarithms 3.6.2 The equation of a straight line 3.6.3 Plotting graphs 3.6.4 Plotting graphs using a spreadsheet 3.7 The ideal gas equation 3.7.1 Dimensional analysis 3.7.2 Interconversion of units 3.7.3 Constants and variables 3.7.4 Proportion 3.7.5 Functions of two variables 3.7.6 Partial differentiation 3.7.7 The differential 3.8 The van der Waals equation 3.8.1 Expression of brackets 3.8.2 Combining limits 3.9 Equilibrium constants 3.9.1 Solving quadratic equations using a formula 3.9.2 Solving quadratic equations iteratively Exercises Problems 4 Solution chemistry 4.1 Introduction 4.2 Concentration of solutions 4.2.1 Concentration of a solution 4.2.2 Dilution of a solution 4.3 Activity 4.4 Molality 4.4.1 Proportion 4.5 Raoult’s Law 4.5.1 Straight line graphs 4.5.2 Proportion 4.6 The Debye-Hückel equation 4.6.1 Logarithms 4.7 Ostwald’s dilution law 4.7.1 Discontinuities 4.8 Partial molar volumes 4.8.1 Functions 4.8.2 Stationary points Exercises Problems 5 Kinetics 5.1 Introduction 5.2 Using a rate equation 5.3 Rates of change 5.4 Zero-order reactions 5.4.1 Integration 5.5 First-order reactions 5.5.1 Integration of 1/x 5.5.2 Rules of logarithms 5.6 Second-order reactions 5.6.1 Partial fractions 5.6.2 Differentiation of logarithmic functions and integration of fractions 5.7 The Arrhenius equation 5.7.1 The exponential function 5.7.2 Inverse functions 5.8 The steady state approximation 5.8.1 Simultaneous equations Exercises Problems 6 Structural chemistry 6.1 Introduction 6.2 Packing fractions of atoms in metals 6.3 Arrangement of atoms in crystals 6.3.1 Pythagoras’ theorem 6.3.2 Pythagoras' theorem in three dimensions 6.4 Bragg’s Law 6.4.1 Trigonometry 6.4.2 Inverses of trigonometric functions 6.5 The unit cell 6.5.1 Unit vectors 6.5.2 Addition and subtraction of vectors 6.5.3 Multiplication of vectors 6.6 X-ray diffraction 6.6.1 Complex numbers 6.7 Symmetry operators 6.7.1 Matrices Exercises Problems 7 Quantum mechanics 7.1 Introduction 7.2 Energy level transitions and appropriate precision 7.3 The photon 7.3.1 Mathematical relationships 7.4 Forces between atoms 7.4.1 Proportionality 7.4.2 Stationary points 7.5 Particle in a box 7.5.1 Complex numbers 7.5.2 Sequences 7.5.3 Inverse functions 7.5.4 Differentiation of fractional indices 7.5.5 Use of standard integrals 7.6 The free particle 7.6.1 The complex conjugate 7.6.2 The modulus of a complex number 7.7 The hydrogen atom wavefunction 7.7.1 Differentiation of a product 7.7.2 Integration by parts 7.7.3 Calculus of the exponential function 7.7.4 Multiple integration 7.7.5 Calculus of the trigonometric functions 7.8 The helium atom 7.8.1 Stationary points 7.9 Hückel theory 7.9.1 Determinants Exercises Problems 8 Spectroscopy 8.1 Introduction 8.2 Calculation of dipole moments 8.3 Dipole and quadrupole moments 8.4 Electromagnetic radiation 8.4.1 Direct and inverse proportion 8.5 The Beer-Lambert Law 8.5.1 Rules of logarithms 8.6 Rotational spectroscopy 8.6.1 Sequences 8.7 Vibrational spectroscopy 8.8 Rotation-vibration spectroscopy 8.9 Nuclear magnetic resonance spectroscopy 8.9.1 Pascal’s Triangle 8.10 Fourier transform spectroscopy 8.10.1 Introduction to Fourier transforms Exercises Problems 9 Statistical mechanics 9.1 Introduction 9.2 Molecular energy distributions 9.3 Configurations 9.3.1 Factorials 9.4 The Boltzmann equation 9.4.1 Differentiation of logarithms 9.4.2 Differentiation of products 9.5 The partition function 9.5.1 Integration by substitution 9.5.2 Calculating a series using a spreadsheet Exercises Problems Appendix A Units A.1 Prefixes A.2 Equivalent units Appendix B Physical constants Answers to exercises Answers to problems Chemical index Mathematical indexReviewsAuthor InformationPaul Yates has a BSc in Chemical Physics, a PhD in Chemistry and an MA in Learning and Teaching in Higher Education. After several years lecturing in physical chemistry at Keele University he moved into educational development. He was subsequently able to combine this experience in the post of Discipline Lead for the Physical Sciences at the Higher Education Academy. He has a long standing interest in the development of mathematical skills and is the author of two textbooks on mathematics for chemists. Since returning to the university sector at Newman University he has developed an interest in the way in which data and metrics is used by various stakeholders including student supporters. He received a Keele University Excellence in Teaching Award, is a Fellow of the Royal Society of Chemistry, a Senior Fellow of the Staff and Educational Development Association, and a Principal Fellow of the Higher Education Academy. Tab Content 6Author Website:Countries AvailableAll regions |
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